Journal sections
Archive
Log in



or
Печатный вестник PRINTED
BULLETIN OF
THE MRSU
Издательство МГОУ Publishing house the
MRSU
CONTACT US:

Our address: 105005, Moscow, Radio street,10a, office 98.

Telephone:
+7 (495) 780-09-42 add. 1740,
+7 (495) 723-56-31

E-mail: evest_mgou@mail.ru,
e-mag@mgou.ru

Work schedule: Monday to Thursday from 10-00 to 17-30,

Friday from 10:00 to 16-00,

lunch break from 13:00 to 14-00.

 

WE IN SOCIAL MEDIA

BK Facebook Telegram Twitter Instagram

Bulletin of the MRSU / Section "Chemistry" / 2012 № 1.

 

Kostrjukova T.S., Vasil'ev N.V.

PRODUCTION OF FLUORINATED β-DIKETONES // Bulletin of the Moscow Regional State University (electronic journal) [Bulletin of the Moscow Regional State University (electronic journal)]. 2012. no. 1. pp. 150-156.


UDC Index: 54.057

Date of publication:

The full text of the article

Downloads count Downloads count: 30

Abstract


The article summarizes the information about the methods of fluorinated β-dicarbonyl compounds production. The attention is given to the classical methods based on both the Claisen condensation and the specific methods, allowing producing a compound which is impossible to synthesize by standard methods. The article describes the problem of synthesizing of aromatic and heteroaromatic fluorinated β-diketones and the process of fluorinated β-dicarbonyl compounds tautomerism.

Key words


fluorinated &beta, -diketone, tautomerism, specific methods preparation fluorinated &beta, -diketones, Claisen condensation, aromatic and heteroaromatic fluorinated &beta

List of references


1. Al'bekov V. S. i dr. Sposob poluchenija ftorsoderzhawih β-diketonov // A.S. SSSR № 1383733, 1987.
2. Bekker P. A., Popkova V. Ja., Knunjanc I. L. Perftorirovannye enoly aliciklicheskogo rjada // Dokl. AN SSSR. 1976. T. 229. № 4
3. Belen'kij G. G., German L. C. Jelektrofil'noe acilirovanie ftorolefinov v prisutstvii pjatiftoristoj sur'my // Izv. AN SSSR. Ser.him. 1974. № 4
4. Burgart Ja. V. Funkcionalizirovannye geterocikly na osnove ftorsoderzhawih 1,3-di- i 1,2,4-trikarbonil'nyh soedinenij: Avtoref. dis. ... d-ra him. nauk. — Ekaterinburg, 2004.
5. Vacadze S. Z. Polidentatnye oligodentatnye organicheskie i kompleksnye ligandy v dizajne i sinteze supramolekuljarnyh arhitektur: Dis. … d-ra him. nauk. — M., 2008.
6. Vacuro K. V., Miwenko G. L. Imennye reakcii v organicheskoj himii. M: Himija, 1976.
7. Isikava N., Kobajasi E. Ftor, himija i primenenie, per. s japonskogo // M.: Mir, 1982. 8. Karpenko N. S. Ftoralkilsoderzhawie 1,3-diketonaty litija. Sintez, stroenie i svojstva: Dis. … kand. him. nauk, Ekaterininburg, 2004.
8. Knunjanc I. L. i dr. Simpozium "Sintez, svojstva i primenenie ftorsoderzhawih ketonov i diketonov". Tezisy dokl. — Sverdlovsk, 1979.
9. Kostrjukova T. S. i dr. Novye kompleksy evropija dlja immunofluorescentnogo analiza biospecificheskih vzaimodejstvij // Vestnik MGOU, serija "Estestvennye nauki". 2009. № 4.
10. Kramarova E. P., Baukov Ju. I., Lucenko I. F. Acilirovanie O-sililzamewennyh enolov angidridami galogenuksusnyh kislot // ZhOH. 1975. № 45.
11. Krotovich I. N. i dr. Simpozium "Sintez, svojstva i primenenie ftorsoderzhawih ketonov i diketonov". Tezisy dokl. — Sverdlovsk, 1979.
12. Osipov S. N. Sintez β-ftorsoderzhawih α-aminokislot, ih proizvodnyh i analogov: Dis. ... d-ra him. nauk. — M., 2002.
13. Pashkevich K. I., Saloutin V. I., Postovskij I. Ja. Ftorsoderzhawie β-diketony // Uspehi himii. 1981. t. 50, vyp.2.
14. Pashkevich K. I. i dr. Polifunkcional'nye ftoralkilsoderzhawie karbonil'nye soedinenija v sinteze geterociklov // Izv. AN. Ser. him. 1998. №7, 16. Sevenard D. V. 2-Poliftoracilzamewennye cikloalkanony i laktony: Struktura i himicheskie svojstva: Diss. … kand. him. nauk. 2001. Ural'skij gos. teh. univer.
15. Stary I. Jekstrakcija helatov. M: Mir, 1966.
16. Titce L., Ajher T. Preparativnaja organicheskaja himija, perevod s nem. — M.: Mir, 1999.
17. Filjakova V. I. Novye polifunkcional'nye ftoralkilsoderzhawie sintony: Metody poluchenija i sinteticheskie vozmozhnosti: Avtoref. dis. … d-ra him. nauk. Ekaterinburg, 1999.
18. Filjakova V. I i dr. Novye ftorsoderzhawie sintony - litievye soli ftorsoderzhawih β-diketonov // Zhurn. org. himii. 1998. T. 34. vyp. 3.
19. Fokin A. V., Kolomiec A. F., Vasil'ev N. V. Ftorsoderzhawie iminy // Usp. himii. 1984. t. 53, № 3.
20. Harvud Dzh. Promyshlennoe primenenie metalloorganicheskih soedinenij, per. s angl. — L.: Himija, 1970.
21. Barkley B., Levine R. The Synthesis of Certain Beta-Diketones Containing Perfluoromethyl and Perfluoro-n-propyl Groups // J. Amer. Chem. Soc. 1951. № 73
22. Filler R. and all. Polyfluoroaryl Dicarbonyl Compounds // J. Org. Chem. 1970. №35.
23. Handbook on the Physics and Chemistry of Rare Earths, ed. by K.A. Gschneidner, Jr., J.-C.G. Bünzli and V.K. Pecharsky. Vol. 35. Binnemans K. Rare-Earth beta-diketonates., Elsevier, 2005.
24. Henne A.L. and all. The Alkaline Condensation of Fluorinated Esters with Esters and Ketones. // J. Amer. Chem. Soc. 1947. № 69.
25. Hudlickiy M, Pavlath A.E. Chemistry of organic fluorine compounds II: a critical review. ACS monograph. 1995.
26. Joshi K.C., Pathak V.N, Bhargava S. Studies in fluorinated β-diketones and related compounds—IV: Synthesis and spectral studies of some new fluorinated β-diketones and their copper chelates J. Inorg. Nucl. Chem. 1977. №39,
27. Joshi K. C., Pathak V. N. Metal chelates of fluorinated 1,3-diketones and related compounds // Coord. Chem. Rev. 1977. № 22.
28. Joshi K.C., Pathak V.N. Synthesis and Biological Activities of Some New 2-Arylamino-4-Fluoroarylthiazoles // Indian J. Chem. 1972. № 10.
29. Lamprey H. Properties and applications of metal acetyl-acetonates // Ann. N. Y. Acad. Sci. 1960. № 88.
30. Mushak, P., Glenn M. T., Savory J. Fluoro-β-diketones and metal fluoro-β-diketonates // Fluorine Chem. Rev. 1973. № 6.
31. Niwa J., Yamazaki M., Takeuchi T. A carbon-13 NMR study of the direction of enolisation of trifluoroacetylacetone // Chem. Letters. 1975.
32. Petrov V.A., Vasiliev N.V. Synthetic Chemistry of Quadricyclane// Current organic Synthesis. 2006. V. 3. № 2. 35. Reid J.C., Calvin M. Some New β-Diketones Containing the Trifluoromethyl Group // J. Amer. Chem. Soc. 1950. № 72.

Лицензия Creative Commons